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6 Cards in this Set

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What is the selection rule associated with vibration-rotation spectroscopy?
ΔJ = ±1
If ΔJ = +1 then what is the letter given to the transition?
This is an R -branch transition.
If ΔJ = -1 then what is the letter given to the transition?
This is a P -branch transition.
What is the equation related to vibration-rotation spectroscopy?

(Hint: ΔE = )
ΔE = ΔEvib + B1J1 (J1 + 1) - B0J0 (J0 + 1)
What equation allows you to work out the vibrational transition level?

(Hint: ΔEvib = )
ΔEvib = hwe + 2hwexe
Name three uses of vibration-rotation spectroscopy...
1) Can be used to determine B of heteronuclear diatomic molecules and therefore their bond lengths

2) Polyatomic structure can be determined

3) High resolution IR spectrometers make good gas sensors.