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9 Cards in this Set
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- Back
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Addition of HX*
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Additional Reagents: HX
What adds: -H, -X Regioselectivity: Markovnikov Stereoselectivity: N/A Rearrangement: Yes |
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Addition of HBr with peroxide*
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Additional Reagents: HBr, peroxide
What adds: -H, -Br Regioselectivity: Anti-Markovnikov Stereoselectivity: N/A Rearrangement: No |
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Acid-Catalyzed Hydration*
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Additional Reagents: H20, H+
What adds: -H, -OH Regioselectivity: Markovnikov Stereoselectivity: N/A Rearrangement: Yes |
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Oxymercuration-Demercuration
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Additional Reagents:
1) Hg(OAc)2, H2O 2) NaBH4 What adds: -H, -OH Regioselectivity: Markovnikov Stereoselectivity: N/A Rearrangement: No |
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Alkoxymercuration-Demercuration
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Additional Reagents:
1) Hg(OAc)2, ROH 2) NaBH4 What adds: -H, -OR Regioselectivity: Markovnikov Stereoselectivity: N/A Rearrangement: No |
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Hydroboration-Oxidation
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Additional Reagents:
1) "BH3" 2) H2O2, -OH What adds: -H, -OH Regioselectivity: Anti-Markovnikov Stereoselectivity: Syn Rearrangement: No |
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Hydrogenation
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Additional Reagents: H2 with Pt, Pd, or Ni
What adds: -H, -H Regioselectivity: N/A Stereoselectivity: Syn Rearrangement: No |
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Simmons-Smith
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Additional Reagents: CH2I2, Zn(Cu)
What adds: -CH2- (triangle) Regioselectivity: N/A Stereoselectivity: Retention of stereochemistry Rearrangement: No |
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Alpha-elimination
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Additional Reagents: CH2X2 or CH3X, with strong base
What adds: -CHX- or -CX2- (triangles) Regioselectivity: N/A Stereoselectivity: Retention of stereochemistry Rearrangement: No |
