- Shuffle
Toggle OnToggle Off
- Alphabetize
Toggle OnToggle Off
- Front First
Toggle OnToggle Off
- Both Sides
Toggle OnToggle Off
Front
How to study your flashcards.
Right/Left arrow keys: Navigate between flashcards.right arrow keyleft arrow key
Up/Down arrow keys: Flip the card between the front and back.down keyup key
H key: Show hint (3rd side).h key
PLAY BUTTON
PLAY BUTTON
11 Cards in this Set
- Front
- Back
|
What does this do to a Thiol?
O₂ |
No Conversion of bonds.
Converts Thiol to disulfide 2 RSH become RSSR |
|
What does it do to a alkoxide ion?
CH₃Br |
Removes metal (Na, K) and attaches methyl to create ether
|
|
What does it do to an alcohol?
H₂SO₄ ----------> heat |
Combines the two alcohols and creates ether and H₂O
|
|
What does it do to an alkene?
CH₃OH ------------> acid |
Converts alkene to alkane.
Adds R group from alcohol to carbocation |
|
What does it do to an epoxide?
1. LiAlH₄ -------------> 2. H₂O |
Breaks epoxide ring leaving OH on more substituted side
|
|
What is the role of Chloro-tert-butyldimethylsilyl (Sylil ether)?
|
Reacts with an alcohol to produce tert-butyldimethylsilyl (t-BuMe₂Si) which Protects primary & secondary alcohols, leaving HCl as a by-product
|
|
What does it do to an alkene?
RCO₃H or MCPBA |
Converts alkene to Alkane
Forms Epoxide Alkane has O bonded to both Carbons from double bond (epoxide). RCOOH is byproduct |
|
What does it do to an alkene?
1. Cl₂, H₂O -----------------> 2. NaOH, H₂O |
Converts alkene to epoxide
|
|
What does it do to an halohydrin, e.g. OHCH₃HC-CHCH₃Cl?
NaOH, H₂O |
Converts halohrydin to epoxide, removing HCl and binding two central Carbons to Oxygen anti to original halogen
|
|
What does it do to an epoxide?
H⁺ ---> H₂O |
Breaks expoxide ring and leaves OH groups trans on both Carbons in ring (racemic)
|
|
What does it do to an epoxide?
NH₃ |
Breaks expoxide ring and leaves OH & Amino groups trans on both Carbons in ring
|
