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EXAMBUSTERS MCAT CHEMISTRY

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Title: EXAMBUSTERS MCAT CHEMISTRY
Description: General Chemistry for the MCAT taken from Exambusters Flash Cards
Number of Cards: 240
Author: artfuldodger739
Created: 2006-02-07
Tags: 240 busters chem chem1 chemistry dat exambuster exambusters examcrackers gen genchem general mcat mcat/dat printed
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Question Answer Note/Hint
Metric Abbreviations: Mega, Kilo, Hecto, Deka, Deci, Centi, Milli, Nano Mega=M; Kilo=k; Hecto=h; Deka =da; Deci =d; Centi =c; Milli=m; Nano=n
Conversion Factor A fraction which expresses an equality between two units of measurement and can be used to convert from one to the other (ex. 1kg/1000g)
Use conversion factors to solve: 1) How many kilograms in 2000 g? 2) How many feet in 60"? 1) (2000g)(1kg/1000g) = 2kg; 2) (60")(1'/12") = 5 ft
Significant digits Digits which are measured. All non-zero digits are significant. Zeros are significant unless they are placeholders
Scientific notation A number expressed as Ax10B. "A" is between 1.00 and 9.99 and "B" is an integer.
Write conversion forumlas: 1) Celsius to Fahrenheit; 2) Celsius to Kelvin 1) ˚f = (1.8 x ˚celsius) + 32; 2) Kelvin = ˚celsius +273
Energy The ability to do work; it is released or absorbed during chemical reactions in the form of heat, light, electricity. (calorie, Joule: 1cal = 4.18J)
Matter A substance that occupies space has mass.
Compare Weight vs. Mass Mass is the amount of matter. Weight measures gravitational force. Mass never varies. Weight can vary.
Compare potential energy and kinetic energy Potential energy is energy due to position. KE is energy of motion.
Explain how to convert a number greater than 1 to scientific notation Move decimal point to left until only 1 digit remains to left. Indicate number of moves as a positive exponent of 10. 3301 = 3.301x10^3
Explain how to convert a number less than 1 to scientific notation Move decimal point to right until only 1 digit remains to left. Indicate number of moves as a negative exponent of 10. (0.00356 = 3.56 x 10-3
Explain the rules for multiplying the numbers in scientific notation Multiply the first numbers and add the exponents. (3x10^5)(2x10^3)= 6x10^8
Explain the rules for dividing the numbers in scientific notation Divide the first numbers and subtract the exponents. (8x10^6)/(2x10^10) = 4x10^-4
Physical properties Properties which can be observed without changing the substance into something different. Color, odor, hardness, density, luster, state, conductivity, solubility, boiling and melting points
Chemical properties A chemical property is observed when a substance changes into a new substance. Iron forms rust in air & water; gasoline burns in oxygen
Physical change Substance changes form or state only. Boiling, melting, freezing, dissolving, grinding, cutting
Chemical change Where new substances are formed with new chemical and physical properties. Oxygen & hydrogen form water; sodium & chlorine form sale (sodium chloride)
Density: Write the general equation and three standard units The mass of a unit volume of a substance. Density = mass/volume = g/mL; g/L; kg/L
Element. List some examples A substance is composed of identical atoms. Gold, silver, oxygen, hydrogen, lead, chlorine, helium, iron, copper, fluorine, arsenic
Compound. List some examples substance composed of two or more elements chemically combined. Water - H2O; Salt - NaCl; Sugar - C6H12O6; Ammonia - NH3
Mixture. List some examples. A combination of substances held together by physical means (dirt, milk, soup, saltwater, granite)
Homogeneous and Heterogeneous mixtures. Provide examples. Homogeneous mixtures are uniform in composition (air, metal alloy, salt water). Heterogeneous mixtures are not uniform in composition (dirt, spaghetti sauce)
Three postulates of Dalton's Atomic Theory 1) An element is composed of identical atoms; 2) Atoms of different elements have different properties; 3) Compounds are atoms of 2 or more elements chemically combined
The Law of Conservation of Mass During a chemical reaction, matter is neither created nor destroyed
The Law of Constant Composition A compound always contains the same elements combined in the same proportions by mass (H2O) is 88% oxygen no matter where it is found)
Law of Multiple Proportions The same elements may combine to form more than one compound. The ratios of atoms are in small whole numbers (H2O and H2O2)
Atomic Mass Unit the mass of a proton or neutron is equal to 1 atomic mass unit. Symbol - "amu"; 1 amu=1.66x10^-24
Atomic Number: What are the atomic numbers of helium, hydrogen, carbon, oxygen? The number of protons in the nucleus of an atom of an element. Helium-2; carbon-6; hydrogen-1; oxygen-8
Mass number The sum of protons plus neutrons n the nucleus of an atom
Isotope Atoms which contain the same numbers of protons but different numbers of neutrons (ex. Hydrogen has 3 isotopes with mass numbers of 1,2,3)
Molecule A group of two or more atoms held together by chemical bonds
Ion (provide examples) An atom or group of atoms which contains a positive or negative electrical charge (ex. Na+; Cl-; SO4^2-)
Cation and Anion (provide examples) cation - positively charged ion (Na+; Fe+2; NH4+; Ag+); anion - negatively charged ion (Cl-; SO4-2; OH-; P-3)
Valence electroncs The electrons found in the outermost energy level of an atom
Oxidation number A number (positive or negative) representing the charge on an ion or atom involved in a chemical bond
Three general rules for determining oxidation numbers 1) Atoms of uncombined elements equal 0; 2) Hydrogen = +1 (in metallic hydrides =-1); 3) Oxygen = -2 (in peroxides =-1); (bonded with fluorine =+2)
Empirical Formula. What are the molecular and empirical formulas of peroxide? An expression which gives the relative numbers of atoms of the elements in a molecule. Expressed as the lowest possible set of integers (H2O2, HO)
Molecular Formula. What is the molecular formula for ammonia? An expression stating the number and kind of each atom present in a molecule of a substance (NH3 has 1 nitrogen atome and 3 hydrogen atoms in each molecule)
Positive Ion: which elements tend to form them? Metals tend to form positive ions by losing electrons (Na → Na+ e-)
Negative Ion: which elements tend to form them? Non-metals form negative ions by gaining electrons (Cl +e- →Cl-)
Write oxidation numbers for ions of: Group IA & IIA; Group VIA & VIIA IA→+1; IIA→+2; VIA→-2; VIIA→-1
Write formula for compounds of: 1) Sodium & Sulfate; 2) Magnesium & Nitrite; 3) Aluminum & Phosphate 1) Na2SO4; 2) Mg(NO2)2; 3) AlPO4
Names of the ionic compounds: 1) FeCL3; 2) FeO; 3) Cu(OH); 3) Cu3PO4 1) iron (III) chloride; 2) iron (II) oxide; 3) copper (II) hydroxide; 4) copper (I) phosphate
10 prefixes used to name covalent compounds Mono=1; Di=2; Tri=3; Tetra=4; Penta=5; Hexa=6; Hepta=7; Octa=8; Nona=9; Deca=10
Forumlas and names of acids formed from: 1) F; 2) Cl; 3) Br; 4) I 1) HF - hydrofluoric acid; 2) HCl - hydrochloric acid; 3) HBr - hydrobromic acid; 4) HI - hydriodic acid
Names of acids: 1)H2SO4; 2) HNO2; 3) H3PO4; 4)HClO 1) sulfuric acid; 2) nitrous acid; 3) phosphoric acid; 4) hypochlorous acid
Write the equation for Percent Composition. What is the percent composition of Ca in CA(OH)2? %=(me/FW)(100%); %= percent composition of the element; me=mass of element in one formula unit; FW = formula weight; (40/74)(100%) = 54% Ca in Ca(OH)2
Atomic Mass A weighted average mass of the atoms of an element (assuming the carbon-12 isotope is exactly 12) (ex. Atomic mass of C=35.45 is calculated from two isotopes. Cl-35 and Cl-36)
Write the equation to calculate the atomic mass of an element Atomic mass of X = ((mx1)(%x1)/100%) + ((mx1)(%x1)/100%)) + etc.; mx1, mx2, mxN = atomic masses of each isotope of element; %x1, %x2, %xN = percent composition of each isotope
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