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146 Cards in this Set
- Front
- Back
chemical categories |
nutrients, food additives, preservatives, toxins. everything that is good or bad in a food is a chemical |
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Pigments |
chlorophylls, carotenoids, anthocyanins, betalains |
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toxins |
solanine, amygdaline |
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Preservatives |
citric acid, benzoic acid
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enzymes |
papain
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Plant tissues |
pigments, toxins, preservatives and enzymes |
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Pigments in fruits and vegetables |
Anthocyanins, Betalains, Carotenoids, Chlorophylls |
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Anthocyanins |
are water soluble compounds ranging from purple to orange. eggplant, radish, red potato |
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Betalains |
purple to red-yellow. Beets |
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Carotenoids |
fat soluble ranging from yellow to red-orange |
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Factors affecting chemistry of plant tissue |
temperature, humidity, washing/soaking, cutting/slicing, heating, freezing |
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Temperature |
reaction rates vary |
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Humidity |
wilting or spoilage |
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Washing/ soaking |
leaching |
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cutting/slicing |
enzymatic change |
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heating |
flavor and texture |
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freezing |
slows reaction |
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Heme |
porphyrin ring. an iron atom at its center with a binding site that can bond any atom that is able to donate a pair of electrons |
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Factors affecting chemistry of animal tissues |
cooking, drying, freezing, pasteurizing |
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cooking |
flavor, color, texture |
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drying |
flavor |
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pasteurizing |
microbial reduction |
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Myoglobin in meat |
purple. reduced Fe+2
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oxymyoglobain |
red. oxygenation and reduced Fe+2 |
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Metmyoglobin |
grayish and brownish. oxidation and oxidized Fe +3 |
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Nitrosylhemochrome |
pink. cured meat (cooked) |
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formulated foods |
food scientists make use of specific chemicals in ingredients to produce a desired result |
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Functionality |
ingredients is defined as the physicochemical properties that affect performance in a food during processing, storage, and preparation |
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types of chemicals in food |
toxic compounds, preservatives, food additives, colors/flavors, nutrients, enzymes, water |
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Toxic compounds |
Bacterial toxins, mycotoxins, Pesticides, Endogenous |
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Endogenous toxins |
solanine, amygdaline, Myristicin, Safrole, Thiocyanate, coumarin, hydrazine |
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Toxicity |
Toxicity of a chemical is related to dose. large amounts of otherwise harmless chemicals may cause problems. Additives with known toxicity are monitored and regulated with a 100X safety factor |
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Toxicity determination |
FDA must approve the uses of all food additives to ensure safety. Threshold level is the dose above which adverse effects are produced |
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Testing additive safety |
all food additives have potential to cause harm or toxicity |
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Preservatives |
work slowing, stopping or killing microbes. salt and sugar are most common, they decrease water activity. |
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food additive |
any substance added to food. |
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intentional additives |
must be approved by the food and drug administration |
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The Ames Test |
developed to identify the mutagenic potential of chemical substances. bacterial cells to chemical substances. |
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indirect additives |
contaminants but are often anticipated at a minimal level |
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indirect additive examples |
antibiotics, Dioxins, dirt, har, hormones, insects, microwave packaging |
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pH control agents |
acidulants: malice acids, tartaric acid, citric acid, vinegar, phosphoric acid. Alkaline compounds: sodium hydroxide |
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colorant |
pigment used to impart color to a food or beverage. is an additive. Natural and artificial colorant. |
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FD&C colorants |
certified as safe for food, drug, or cosmetic applications |
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Dyes |
water soluble for entire foods |
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Lakes |
insoluble for food surfaces |
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Exempt colorants |
Annatto from seeds of a tropical evergreen. cochineal from dried cochineal insects. caramel from non enzymatic thermal processing of sugars. paprika extract |
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character-impact compounds |
are associated with particular products. ex- Benzzaldehyde: cherry or almond. Isoamyl acetate: banana |
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Maillard reaction products |
are made by heating amino acids with reducing sugars
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extract |
alcohol as solvent |
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essential oil |
steam distillation |
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oleoresin |
oil-soluble extract |
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Protein hydrolysates |
perform as both flavorings and enhancers |
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hydrolyzed vegetable protein |
is derived from soybeans |
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monosodium glutamate |
is a flavor enhancer for the savory (umami) character in meat products |
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carbohydrates |
monosaccharides, disaccarides, oligosaccharides, polysaccharides, dietary fiber |
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gelatinization |
hydrated starch granules swell during heating to release soluble starch molecules that provide thickening |
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vegetable gums |
long chain polymers that can be linear or branched. uses are thickening, gelling and binding Ex: Xanthan gum, Guar gum, Carrageenan and alginate, gum arabic |
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dietary fiber |
does not provide energy but does avert or decrease some problems |
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essential amino |
acids are one that the body can't synthesize. lysine, methionine, tryptophan, valine |
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excessive protein |
can cause problems. lack of glucose for the brain. ketoacidosis. hush urea in urine. |
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sterols |
required for proper brain function and to produce key hormones. progesterone and testosterone |
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lipoproteins |
water soluble substances that transport fat and cholesterol in blood. |
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low-density lipoproteins (LDLs) |
carries cholesterol from liver to body cells |
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very-low-density lipoproteins (VLDLs) |
carry cholesterol and TGs from liver to body |
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High-density lipoproteins (HDLs) |
carry cholesterol back to the liver |
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excessive lipids |
intake will accumulate in arteries (heart disease) and contribute to overall weight gain (obesity) |
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lipid intake |
less than or equal to 30% of calories from fat. less than or equal to 10% of calories from saturated fat. no more than 300 mg of cholesterol |
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gycogen |
animal starch stored in muscles as a source of energy. when glycogen requirements are met, excess glucose is converted to fat |
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excessive carbohydrates |
besides the accumulation of fat associated with eating too many calories, there are additional problems. dental caries, diabetes |
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recommended carb intake |
lower limit: 55% of caloric intake. upper limit: 75% of caloric intake. sugars less than 10% of caloric intake. fiber: 20-35 g/day |
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water soluble vitamins |
includes B- vitamins and vitamin C |
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Fat soluble vitamins |
include A,D, E, and K |
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Ethanol |
alcohol. provides 7 kcal/gram and is the 4th source of calories |
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excessive consumption of alcohol |
weight gain, impaired motor skills, poor judgement |
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milling |
removes dietary fiber so many people now seek whole grain products |
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grain |
source of carbohydrates and dietary fiber. oat fiber is good form of fiber |
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vegetable fiber |
high in pectin and lower in cellulose than fiber from grain |
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vegetables |
provide minerals, vitamins and dietary fiber. high in moisture and low in fat and sugar |
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fruits |
contribute vitamins, minerals and fiber to the diet. have more sugar and less starch than vegetables. processed juices have less dietary fiber than whole fruits |
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Milk |
high in calcium, protein, potassium and vitamin D. cheeses high in fat. lactose-intolerant individuals may consume yogurt which is low in lactose but delivers calcium and vitamin D |
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Meat and Beans |
protein is primary nutrient. many also rich in B-vitamins, iron and zinc. animal products tend to be higher in fat, minerals, and balances proteins |
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oils |
fats are solid at room temperature and have higher levels of saturated fats than oils. peanuts, soybeans, sunflower seeds and canola seeds are sources. |
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essential fatty acids |
oils provide this. needed for absorption of fat-soluble vitamins |
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Bioavability |
refers to the degree to which nutrients are digested and absorbed |
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processed, formulated, chilled and prepared foods |
food processing may diminish some nutrients, but enrichment is also possible to replace losses. primary purposes of processing are to increase shelf-life or safety and to reduce waste |
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enzymes |
responsible for the digestion or breakdown of food molecules into absorbable units. are protein molecules that cause chemical reactions to occur without being altered in the process. |
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lipids and 3 types |
defined as chemical compounds that are soluble in organic solvents but not soluble in water. 3 groups of lipids: triglycerides, phospholipids, cholesterol |
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saturated |
fatty acids are saturated if there are no carbon to carbon double bonds |
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unsaturated |
fatty acids are unsaturated if there are one or more double bonds. oils more unsaturated and thus have a lower melting point than fats |
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fractionation |
involves splitting oils into high and low melting point components |
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hydrogenation |
forced addition of hydrogen atoms to the unsaturated bonds of fatty acids to raise the melting point of the fat (harden) |
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Hydrolysis |
breakdown of triglycerides is the breakdown of triglycerides into glycerol and fatty acids |
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interesterification |
rearrangement or recombination of fatty acids from a triglyceride |
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oxidation |
result of oxygen reacting with the double bonds of unsaturated fatty acids to produce a rancid flavor or aroma |
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polymerization |
fatty acids can occur after fatty acids are hydrolyzed from glycerol |
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proteins |
important macronutrients and provide essential amino acids. provide structure in foods and often serve as enzymes in reactions. are Polymers of amino acids. every protein has an acid end and an amino end |
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primary |
linear sequence of amino acids |
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secondary |
refers to the alpha helix or beta sheet configuration |
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tertiary |
describes the 3 dimensional shape of the protein molecule |
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Quaternary |
overall spatial structure if the protein has more than one polypeptide |
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denaturation |
unfolding of protein structure without disrupting covalent bonds. starches, lipids and vitamins do not denature |
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hydrolysis |
results in degradation to primary structure by enzymes, heat, extremes of pH |
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enzymes |
specialized proteins that catalyze specific reactions converting substrate to products |
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enzymatic hydrolysis |
utilizes enzymes to break large molecules into smaller fragments. carbs, lipids |
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enzymatic oxidation-reduction |
reactions involve enzymes that cause changes in chemical structures. polyphenol oxidase |
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enzymatic polymerization |
involve the condensation f molecules into polymers |
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water |
most abundant chemical in foods. may be solid liquid or gas. known as a the universal solvent. important for safety and quality of products |
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water activity |
is a measure of the availability of water molecules. calculated as the ratio of water vapor pressure of the substance divided by the vapor pressure of pure water at the same temperature |
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water holding capacity |
ability to retain moisture during application of external forces like heating, grinding, and pressing |
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dispersions |
many foods and beverages are dispersions where a discontinuous phase is dispersed in a continuous phase. ex: solutions, gels, suspensions, foams, and emulsions |
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emulsions |
two phase system in which one phase is dispersed in the other. oil in water and water in oil are examples. |
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absorption |
occurs when digested nutrients enter the bloodstream through capillaries of the small intestine. |
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what must pass through mucosal cells lining the intestine? |
Nutrients |
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simple diffusion |
small lipids and water |
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facilitated diffusion |
water-soluble vitamins |
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active transport |
glucose and amino acids |
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transport |
the delivery of nutrients and oxygen to all of the body's cells by the vascular system. Exchange of nutrients and wastes takes place across the walls of capillaries |
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osteoporosis |
calcium deficiency diseases |
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microbes |
responsible for almost all food borne illness and cause most food spoilage |
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food microbiology |
study of the physiology, genetics, growth characteristics, survival, and behavior of microbes |
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microorganisms |
are living entities that are too small to be seen with the naked eye |
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Bacteria |
unicellular prokaryotes found almost everywhere |
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Fungi |
molds and Yeasts |
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Molds |
multi or unicellular eukaryotes. growth is evidenced by mycelium |
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yeasts |
unicellular eukaryotes. grow faster than molds. oval |
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Protozoa |
single-celled eukaryotes. do not grow in foods, but are parasites that require a host to complete their life cycle |
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Viruses |
all viruses are parasitic and are generally host-specific. |
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Microbe reproduction |
most reproduction is by cell division under optimum conditions, division may take a little as 30 minutes |
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Lag |
no or slow growth, getting used to the environment |
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Log |
rapid growth |
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extrinsic factors |
environmental characteristics that surround food. temperature, relative humidity, gaseous environment |
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Intrinsic factors |
food composition and characteristics that influence microbial growth in the food. EX- water activity, pH, nutrients |
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control of microorganisms |
food, acidity, temperature, time, oxygen, moisture |
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nutrient requirements |
vary with the type of organism, but most foods provide high nutrient availability for microorganisms |
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Acidity |
the pH in which microbes live is a particular range defined by minimum, maximum, and optimum |
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acid foods |
those that have a natural pH of 4.6 or less |
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acidified foods |
low acid foods to which acids are added |
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low acid foods |
those with a pH greater than 4.6 and aw of .85 or more |
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anaerobes |
cannot tolerate oxygen |
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aerobes |
require oxygen |
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inhibitors |
chemical compounds that slow the growth of microbes |
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bacteriocins |
chemicals produced by bacteria that inhibit others |
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fermentation |
biological process in which microorganisms induce a series of chemical reactions leading to food preservationf |
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spoilage organsims |
common spoilage bacterial genera. ex- canned foods, cold cuts, bread |
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intoxication |
a toxin is formed by the microorganism prior to ingestion |
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infection |
the live microorganism must be ingested to cause disease |