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146 Cards in this Set

  • Front
  • Back

chemical categories

nutrients, food additives, preservatives, toxins. everything that is good or bad in a food is a chemical

Pigments

chlorophylls, carotenoids, anthocyanins, betalains

toxins

solanine, amygdaline

Preservatives

citric acid, benzoic acid


enzymes

papain


Plant tissues

pigments, toxins, preservatives and enzymes

Pigments in fruits and vegetables

Anthocyanins, Betalains, Carotenoids, Chlorophylls

Anthocyanins

are water soluble compounds ranging from purple to orange. eggplant, radish, red potato

Betalains

purple to red-yellow. Beets

Carotenoids

fat soluble ranging from yellow to red-orange

Factors affecting chemistry of plant tissue

temperature, humidity, washing/soaking, cutting/slicing, heating, freezing

Temperature

reaction rates vary

Humidity

wilting or spoilage

Washing/ soaking

leaching

cutting/slicing

enzymatic change

heating

flavor and texture

freezing

slows reaction

Heme

porphyrin ring. an iron atom at its center with a binding site that can bond any atom that is able to donate a pair of electrons

Factors affecting chemistry of animal tissues

cooking, drying, freezing, pasteurizing

cooking

flavor, color, texture

drying

flavor

pasteurizing

microbial reduction

Myoglobin in meat

purple. reduced Fe+2


oxymyoglobain

red. oxygenation and reduced Fe+2

Metmyoglobin

grayish and brownish. oxidation and oxidized Fe +3

Nitrosylhemochrome

pink. cured meat (cooked)

formulated foods

food scientists make use of specific chemicals in ingredients to produce a desired result

Functionality

ingredients is defined as the physicochemical properties that affect performance in a food during processing, storage, and preparation

types of chemicals in food

toxic compounds, preservatives, food additives, colors/flavors, nutrients, enzymes, water

Toxic compounds

Bacterial toxins, mycotoxins, Pesticides, Endogenous

Endogenous toxins

solanine, amygdaline, Myristicin, Safrole, Thiocyanate, coumarin, hydrazine

Toxicity

Toxicity of a chemical is related to dose. large amounts of otherwise harmless chemicals may cause problems. Additives with known toxicity are monitored and regulated with a 100X safety factor

Toxicity determination

FDA must approve the uses of all food additives to ensure safety. Threshold level is the dose above which adverse effects are produced

Testing additive safety

all food additives have potential to cause harm or toxicity

Preservatives

work slowing, stopping or killing microbes. salt and sugar are most common, they decrease water activity.

food additive

any substance added to food.

intentional additives

must be approved by the food and drug administration

The Ames Test

developed to identify the mutagenic potential of chemical substances. bacterial cells to chemical substances.

indirect additives

contaminants but are often anticipated at a minimal level

indirect additive examples

antibiotics, Dioxins, dirt, har, hormones, insects, microwave packaging

pH control agents

acidulants: malice acids, tartaric acid, citric acid, vinegar, phosphoric acid. Alkaline compounds: sodium hydroxide

colorant

pigment used to impart color to a food or beverage. is an additive. Natural and artificial colorant.

FD&C colorants

certified as safe for food, drug, or cosmetic applications

Dyes

water soluble for entire foods

Lakes

insoluble for food surfaces

Exempt colorants

Annatto from seeds of a tropical evergreen. cochineal from dried cochineal insects. caramel from non enzymatic thermal processing of sugars. paprika extract

character-impact compounds

are associated with particular products. ex- Benzzaldehyde: cherry or almond. Isoamyl acetate: banana

Maillard reaction products

are made by heating amino acids with reducing sugars


extract

alcohol as solvent

essential oil

steam distillation

oleoresin

oil-soluble extract

Protein hydrolysates

perform as both flavorings and enhancers

hydrolyzed vegetable protein

is derived from soybeans

monosodium glutamate

is a flavor enhancer for the savory (umami) character in meat products

carbohydrates

monosaccharides, disaccarides, oligosaccharides, polysaccharides, dietary fiber

gelatinization

hydrated starch granules swell during heating to release soluble starch molecules that provide thickening

vegetable gums

long chain polymers that can be linear or branched. uses are thickening, gelling and binding Ex: Xanthan gum, Guar gum, Carrageenan and alginate, gum arabic

dietary fiber

does not provide energy but does avert or decrease some problems

essential amino

acids are one that the body can't synthesize. lysine, methionine, tryptophan, valine

excessive protein

can cause problems. lack of glucose for the brain. ketoacidosis. hush urea in urine.

sterols

required for proper brain function and to produce key hormones. progesterone and testosterone

lipoproteins

water soluble substances that transport fat and cholesterol in blood.

low-density lipoproteins (LDLs)

carries cholesterol from liver to body cells

very-low-density lipoproteins (VLDLs)

carry cholesterol and TGs from liver to body

High-density lipoproteins (HDLs)

carry cholesterol back to the liver

excessive lipids

intake will accumulate in arteries (heart disease) and contribute to overall weight gain (obesity)

lipid intake

less than or equal to 30% of calories from fat. less than or equal to 10% of calories from saturated fat. no more than 300 mg of cholesterol

gycogen

animal starch stored in muscles as a source of energy. when glycogen requirements are met, excess glucose is converted to fat

excessive carbohydrates

besides the accumulation of fat associated with eating too many calories, there are additional problems. dental caries, diabetes

recommended carb intake

lower limit: 55% of caloric intake. upper limit: 75% of caloric intake. sugars less than 10% of caloric intake. fiber: 20-35 g/day

water soluble vitamins

includes B- vitamins and vitamin C

Fat soluble vitamins

include A,D, E, and K

Ethanol

alcohol. provides 7 kcal/gram and is the 4th source of calories

excessive consumption of alcohol

weight gain, impaired motor skills, poor judgement

milling

removes dietary fiber so many people now seek whole grain products

grain

source of carbohydrates and dietary fiber. oat fiber is good form of fiber

vegetable fiber

high in pectin and lower in cellulose than fiber from grain

vegetables

provide minerals, vitamins and dietary fiber. high in moisture and low in fat and sugar

fruits

contribute vitamins, minerals and fiber to the diet. have more sugar and less starch than vegetables. processed juices have less dietary fiber than whole fruits

Milk

high in calcium, protein, potassium and vitamin D. cheeses high in fat. lactose-intolerant individuals may consume yogurt which is low in lactose but delivers calcium and vitamin D

Meat and Beans

protein is primary nutrient. many also rich in B-vitamins, iron and zinc. animal products tend to be higher in fat, minerals, and balances proteins

oils

fats are solid at room temperature and have higher levels of saturated fats than oils. peanuts, soybeans, sunflower seeds and canola seeds are sources.

essential fatty acids

oils provide this. needed for absorption of fat-soluble vitamins

Bioavability

refers to the degree to which nutrients are digested and absorbed

processed, formulated, chilled and prepared foods

food processing may diminish some nutrients, but enrichment is also possible to replace losses. primary purposes of processing are to increase shelf-life or safety and to reduce waste

enzymes

responsible for the digestion or breakdown of food molecules into absorbable units. are protein molecules that cause chemical reactions to occur without being altered in the process.

lipids and 3 types

defined as chemical compounds that are soluble in organic solvents but not soluble in water. 3 groups of lipids: triglycerides, phospholipids, cholesterol

saturated

fatty acids are saturated if there are no carbon to carbon double bonds

unsaturated

fatty acids are unsaturated if there are one or more double bonds. oils more unsaturated and thus have a lower melting point than fats

fractionation

involves splitting oils into high and low melting point components

hydrogenation

forced addition of hydrogen atoms to the unsaturated bonds of fatty acids to raise the melting point of the fat (harden)

Hydrolysis

breakdown of triglycerides is the breakdown of triglycerides into glycerol and fatty acids

interesterification

rearrangement or recombination of fatty acids from a triglyceride

oxidation

result of oxygen reacting with the double bonds of unsaturated fatty acids to produce a rancid flavor or aroma

polymerization

fatty acids can occur after fatty acids are hydrolyzed from glycerol

proteins

important macronutrients and provide essential amino acids. provide structure in foods and often serve as enzymes in reactions. are Polymers of amino acids. every protein has an acid end and an amino end

primary

linear sequence of amino acids

secondary

refers to the alpha helix or beta sheet configuration

tertiary

describes the 3 dimensional shape of the protein molecule

Quaternary

overall spatial structure if the protein has more than one polypeptide

denaturation

unfolding of protein structure without disrupting covalent bonds. starches, lipids and vitamins do not denature

hydrolysis

results in degradation to primary structure by enzymes, heat, extremes of pH

enzymes

specialized proteins that catalyze specific reactions converting substrate to products

enzymatic hydrolysis

utilizes enzymes to break large molecules into smaller fragments. carbs, lipids

enzymatic oxidation-reduction

reactions involve enzymes that cause changes in chemical structures. polyphenol oxidase

enzymatic polymerization

involve the condensation f molecules into polymers

water

most abundant chemical in foods. may be solid liquid or gas. known as a the universal solvent. important for safety and quality of products

water activity

is a measure of the availability of water molecules. calculated as the ratio of water vapor pressure of the substance divided by the vapor pressure of pure water at the same temperature

water holding capacity

ability to retain moisture during application of external forces like heating, grinding, and pressing

dispersions

many foods and beverages are dispersions where a discontinuous phase is dispersed in a continuous phase. ex: solutions, gels, suspensions, foams, and emulsions

emulsions

two phase system in which one phase is dispersed in the other. oil in water and water in oil are examples.

absorption

occurs when digested nutrients enter the bloodstream through capillaries of the small intestine.

what must pass through mucosal cells lining the intestine?

Nutrients

simple diffusion

small lipids and water

facilitated diffusion

water-soluble vitamins

active transport

glucose and amino acids

transport

the delivery of nutrients and oxygen to all of the body's cells by the vascular system. Exchange of nutrients and wastes takes place across the walls of capillaries

osteoporosis

calcium deficiency diseases

microbes

responsible for almost all food borne illness and cause most food spoilage

food microbiology

study of the physiology, genetics, growth characteristics, survival, and behavior of microbes

microorganisms

are living entities that are too small to be seen with the naked eye

Bacteria

unicellular prokaryotes found almost everywhere

Fungi

molds and Yeasts

Molds

multi or unicellular eukaryotes. growth is evidenced by mycelium

yeasts

unicellular eukaryotes. grow faster than molds. oval

Protozoa

single-celled eukaryotes. do not grow in foods, but are parasites that require a host to complete their life cycle

Viruses

all viruses are parasitic and are generally host-specific.

Microbe reproduction

most reproduction is by cell division under optimum conditions, division may take a little as 30 minutes

Lag

no or slow growth, getting used to the environment

Log

rapid growth

extrinsic factors

environmental characteristics that surround food. temperature, relative humidity, gaseous environment

Intrinsic factors

food composition and characteristics that influence microbial growth in the food. EX- water activity, pH, nutrients

control of microorganisms

food, acidity, temperature, time, oxygen, moisture

nutrient requirements

vary with the type of organism, but most foods provide high nutrient availability for microorganisms

Acidity

the pH in which microbes live is a particular range defined by minimum, maximum, and optimum

acid foods

those that have a natural pH of 4.6 or less

acidified foods

low acid foods to which acids are added

low acid foods

those with a pH greater than 4.6 and aw of .85 or more

anaerobes

cannot tolerate oxygen

aerobes

require oxygen

inhibitors

chemical compounds that slow the growth of microbes

bacteriocins

chemicals produced by bacteria that inhibit others

fermentation

biological process in which microorganisms induce a series of chemical reactions leading to food preservationf

spoilage organsims

common spoilage bacterial genera. ex- canned foods, cold cuts, bread

intoxication

a toxin is formed by the microorganism prior to ingestion

infection

the live microorganism must be ingested to cause disease