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68 Cards in this Set

  • Front
  • Back

Atomic number

The number of protons in the nucleus of an atom.

Mass number

The number of protons and neutrons in the nucleus of an atom.

Relative isotopic mass

The mass of an atom of an isotope compared with 1/12 of the mass of an atom ofC-12.

Relative atomic mass

The weighted mean mass of an atom of an element compared with 1/12 of the mass of an atom of C-12.

Isotopes

Atoms of the same element with a different number of neutrons.



Atomic orbital

A region within an atom that can hold up to two electrons, with opposite spins.

s/p/d block element

Highest energy sub-shell is a s/p/d sub-shell.

Acid

Release H+ ions in solution (proton donor).

Base

A proton acceptor.

Alkali

A soluble base that release OH- ions when in solution.

Salt

A compound produced when a H+ ion from an acid is replaced by a metalor another positive ion, such as the ammonium ion.

Mole

The amount of substance containing as many particles as there are carbon atoms inexactly 12g of C-12.

Avagdro's constant

The number of particles per mole of a substance (6.02x1023).

Molar mass

The mass, in g, per mole of a substance. Units are gmol-1.

Empirical formula

The simplest whole number ratio of atoms of each element present in a compound.

Molecular formula

The actual number of atoms of each element in a molecule.

Waters of crystallisation

The water present in a compound giving the compound a crystalline appearance.

Anhydrous

When all the waters of crystallisation havebeen removed from a compound.

Hydrated

When water of crystallisation is present in a crystal compound.

First ionisation energy

The energy required to remove one electron from each atom in one mole of gaseous atoms to form one mole of gaseous 1+ ions. Units are kJ mol-1.

Successive ionisation energy

A measure of the energy required to remove each electron in turn.

Ionic bond

The electrostatic attraction between oppositely charged ions.

Covalent bond

The sharing of a pair of electrons between two atoms.

Dative (co - ordinate) bond

The sharing of a pair of electrons between two atoms where only one of the atomssupplies both the electrons shared.

Electronegativity

The ability of an atom to attract the bonding electrons towards itself in acovalent bond.

Metallic bonding.

The attraction of positive metal ions to delocalised electrons.

Periodicity

The repeating pattern of trends across different periods.

Oxidation number

A measure of the number of electrons that an atom uses to bond with atoms of adifferent element.

Oxidation

The loss of electrons / an increase in oxidation number (state).

Oxidising agent

A reagent which oxidises another species (gets reduced itself).

Reduction

The gain of electrons / a decrease in oxidation number (state).

Reducing agent

A reagent which reduces another species (gets oxidised itself).

Redox

A reaction where both oxidation and reduction take place.

Displacement reaction

A reaction in which a more reactive element displaces a less reactive element from an aqueous solution of its halide ions.

Disproportionation

A reaction in which an element is simultaneously oxidised and reduced.

Hydrogen bonds

A dipole-dipole attraction between a slightly positive hydrogen on one molecule and a lone pair of electrons on a highly electronegative atom (N, O, F) of another molecule.

Hydrocarbon

A compound containing only hydrogen and carbon only.

Homologous series

A series of organic compounds having the same functional group but with each successive member differing by CH2.

Functional group

A group of atoms responsible for the characteristic reactions of a compound.

Saturated

Containing single bonds only.

Unsaturated

Containing at least one carbon - carbon double bond.

Empirical formula

The simplest whole number ratio of atoms of each element present in a compound.

Molecular formula

The actual number of atoms of each element in a molecule.

Structural isomers.

Compounds with the same molecular formula but a different structural formula.

Stereoisomers

Compounds with the same structural formula but a different arrangement of atoms in the space.

E/Z Isomerism

An example of stereoisomerism, in terms of restricted rotation about a double bond and the requirement for two groups to be attached to each carbon of the carbon - carbon double group.

CIS - TRANS Isomerism

A special case of E/Z isomerism in which two of the substituent groups are the same.

Fractional distillation

Separation of a liquid mixture into fractions with different boiling points.

Catalytic cracking

The breaking down of long chained saturated hydrocarbons to form more useful and shorter chained alkanes and alkenes.

Biofuel

A fuel that is derived from recently living material such as plants or from the waste of animals.

Curly arrow

The movement of an electron pair, showing either the breaking or formation of a covalent bond

Radical

A species with an unpaired electron.

Homolytic fission

The breaking of a covalent bond where the shared pair of electrons are split equally forming two radicals.

Heterolytic fission

The breaking of a covalent bond where the shared pair of electrons are not equally split, forming a cation and an anion.

Electrophile

Species attracted to an electron rich centre where it accepts a pair of electrons to form a new covalent bond.

Nucleophile

A species that is attracted to an electron deficient centre where it donates a pair of electrons to form a new covalent bond.

Exothermic

Heat is given out to the surroundings (reactants lose energy).

Endothermic

Heat is taken from the surroundings (reactants gain energy).

Activation energy

The minimum energy required to start a reaction by the breaking of bonds.

Standard conditions

A pressure of 1 atmosphere, 25 degrees celcius, and a concentration of 1.00 moldm - 3.

Standard enthalpy change of reaction

The enthalpy change that accompanies a reaction in the molar quantities expressed in a chemical equation (under standard conditions).

Standard enthalpy change of formation

The enthalpy change that takes place when one mole of a compound is formed from its constituent elements (in standard conditions).

Standard enthalpy change of combustion

The enthalpy change that takes place when one mole of a substance reacts completely with oxygen (in standard conditions).

Average bond enthalpy

The average enthalpy change that takes place when breaking by homolytic fission, one mole of a given type of bond in the molecules of a gaseous species.

Catalyst

Speeds up a reaction without being consumed by the overall reaction.

Volatility

The ease at which a liquid turns into a gas.

Dynamic equilibrium

The equilibrium that exists in a closed system when the rate of forward reaction is equal to the rate of the reserve reaction.

Le Chatelier's principle

When a system in dynamic equilibrium is subjected to change, the position of equilibrium will shift to minimise the change.