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26 Cards in this Set

  • Front
  • Back

Functional group

The part of the organic molecule responsible for its chemical reactions

Homologous series

A series of organic compounds with the same functional group but with each successive number different by CH2

Nomenclature

A system of naming compounds

General formula

The simplest algebraic formula of a member of a homologous series e.g the general formula for alkanes is CnH2n+2

Structural formula

The formula showing the minimal detail for the arrangement of atoms in a molecule

Skeletal formula

A simplified organic formula with H atoms removed from alkyl chains, leaving just a carbon skeleton and associated functional groups

Structural isomer

Compounds with the same molecular formula but different structural formulae

Sterioisomerism

Arrangement of compounds with the same structural formula but a different arrangement of atoms in space

Saturated hydrocarbons

Hydrocarbons with only single bonds

Unsaturated hydrocarbons

Hydrocarbons with a multiple carbon to carbon Bond

Homolytic fission

The breaking of a covalent bond with one of the bonded electrons going to each atom, forming two radicals

Heterolytic fission

The breaking of a covalent bond forming a cation (positive ion) and an anion (negative ion)

Nucleophile

An atom or group of atoms that is attracted to an electron deficient carbon atom, where it donates a pair of electrons to form new covalent bond

Electrophile

An atom / group of atoms that is attracted to an electron rich centre, where it accepts a pair of electrons

Free radical

Unstable molecules that can damage the cells in your body. Formed when atoms /molecules gain or lose electrons

Pie bond

A bond formed by the sideways overlap of two p orbitals containing two electrons and with electron density concentrated above and below line joining nuclei of bonding atoms

Sigma bond

The bond formed by the overlap of orbitals from each bonding atom, consisting of two electrons and with electron density centred around line directly between the nuclei of atoms

Addition polymerisation

Formation of a very long molecular chain (addition polymer) by repeated addition reactions of many unsaturated alkene molecules (monomers)

Homologous series

Series of organic compounds with the same functional group but with each successive member differing by CH2

Functional group

The part of the organic molecule responsible for its chemical reactions

Alkyl

A side-chain formed by removing a H atom removed from an alkane parent chain. Any alkyl group is often shown as 'R'.

Aliphatic

Containing C atoms joined together in unbranched (straight) or branched chains (no benzene rings)

Alicyclic

Containing carbon atoms join together in a ring that is not aromatic

Aromatic

Containing one of more benzene rings

Saturated

Containing single bonds only

Unsaturated

Containing multiple carbon-carbon bond