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18 Cards in this Set

  • Front
  • Back
According to Arrhenius, what is the definition of an acid and a base ?
1. Acid: A substance that when dissolved with water, it increases the concentration of hydrogen ions
2. Base: A substance that when dissolved with water, it increases the concentration of hydroxide ions
What is a Bronsted-Lowry acid and base ?
1. Acid: A substance that willingly donates a proton
2. Base: A substance that willingly receives/accepts a proton
What are species called that can both act as an acid or a a base ?
Amphiprotic or amphoteric.
How does the Bronsted-Lowry concept enlarge Arrhenius' concept ?
1. Expands it to include substances that only contain H+ ions
2. Includes ions and molecules
3. Enables us to write acid-base reactions that are not just restricted to aqueous solutions
4. Allows some species to sometimes be both an acid or a base
What is the conjugate acid and base of water ?
Acid - H+ or H3O+
Base- OH-
True or false: It is safe to assume that weak acids will yield weak conjugate bases.
True.
True or false: In any acid-base reaction, the equilibrium will favor the reaction that gives the proton to the weakest base.
False. It will favor the reaction that gives it to the strongest base.
What is self-ionization in water ?
A process where two water molecules react with one another to form one hydronium ion and one hydroxide ion.
What is the ion product constant ?
1.0 x 10^-14 = Kw = [H+][OH-].
What is the equation for pH and pOH respectively ?
pH = -log[H+]

pOH = -log[OH-]
What will pH + pOH always equal ?
14.
How would you calculate [H+] from pH ?
[H+] = 10^-pH.
True or false: In a very strong poliprotic acid, the [H+] = [acid].
False. This is true for a very strong monoprotic acid.
Give the expression for the acid dissociation constant.
k = ([H+][A-]) / [HA]
What can you deduce from a large Ka value ?
That the acid is strong because it almost dissociated completely.
True or false: The acid strength of an acid decreases with an increasing negative charge.
True.
True or false: The acid strength of an acid decreases with an increase in number of oxygen atoms inside that molecule.
False. The acid strength increases.
What is the definition of a Lewis acid and base, respectively ?
1.Acid- A electron pair acceptor/receiver
2. Base- An electron pair donator