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12 Cards in this Set

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S orbital shape?

Spherical

P orbital shape

Dumbbell?!

Shell structure up to n=4

How are orbitals often displayed?

As boxes with arrows indicating spin.

You could show it with a pen.

How do electrons fill orbitals?

They join empty orbitals, then pair up.

How can electron configuration be shown in shorthand?

[The previous noble gas] + any further subshells

What happens with 4s and 3d?

4s fills first, but once filled the 3d energy level falls below 4s, so:


4s fills and empties first.

Period trend of 1st ionisation energy:

Across a period elements have the same number of quantum shells.


First ionisation energy increases (in general), as the is similar electron shielding, nuclear attraction increases, atomic radius decreases.

Group trends of first ionisation energy:

Atomic radius increases, more inner shell, so shielding increases, more nuclear attraction, so first ionisation energy decreases.

What is first ionisation energy?

The energy required to remove one electron from each atom in 1 mole of gaseous atoms of an element to form one more of gaseous 1+ ions.

Why does 1st ionisation energy fall from Be to B and from N to O?

Be->B 2p has a higher energy level than 2s, so it is easier to remove an electron, so 1st ionisation energy of Be is higher than B.


N->O 2p³ to 2p⁴ 2p³ has one electron in each orbital. I'm 2p⁴ there is a paired electron. These electrons repel, so 1st ionisation energy of O is lower than N.

Order of filling orbitals